First you will need to edit your default javascript file called “quicktags.js”.
vi /wp-includes/js/quicktags.js
Find something that looks like the entry below. This will be your Bold or if you prefer HTML language strong button.
edButtons[edButtons.length] = new edButton('ed_strong' ,'b' ,'' ,'' ,'b' );
You can add anything after that or before that. For example I use WP-CodeBox for all of my code entries. It puts them in these pretty boxes with some nice features if I encase my code in a pre statement and tell it what type of language. So I simply added a new button called pre and adds the pre statement to the beginning and to the end of the highlighted text. I also told it to define the language by default as just text.
Please note WP-CodeBox will not handle HTML pre syntax so I have modified it like so.
.
edButtons[edButtons.length] = new edButton('ed_pre' ,'pre' ,'' ,''
,'c'
);